N-(2,5-Dichlorophenyl)benzenesulfonamide
نویسندگان
چکیده
In the title compound, C(12)H(9)Cl(2)NO(2)S, the conformation of the N-H bond is syn to the 2-chloro group and anti to the 3-chloro group of the aniline benzene ring. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of 66.4 (2)°. The two rings form a dihedral angle of 73.3 (1)° and an intra-molecular N-H⋯Cl hydrogen bond occurs. The crystal structure features chains linked by N-H⋯O hydrogen bonds.
منابع مشابه
4-Chloro-N-(2,3-dichlorophenyl)benzenesulfonamide
In the title compound, C(12)H(8)Cl(3)NO(2)S, the two aromatic rings are tilted relative to each other by 56.5 (1)°. The crystal structure features centrosymmetric dimers in which mol-ecules are linked by N-H⋯O hydrogen bonds.
متن کاملN-(3,5-Dichlorophenyl)benzenesulfonamide
In the crystal structure of the title compound, C(12)H(9)Cl(2)NO(2)S, the aromatic rings are aligned at 57.0 (1)°. The mol-ecules form chains via inter-molecular N-H⋯O hydrogen bonds.
متن کامل2,4-Dichloro-N-(3,4-dichlorophenyl)benzenesulfonamide
In the crystal structure of the title compound, C(12)H(7)Cl(4)NO(2)S, the conformation of the N-H bond is syn to the meta-chloro residue in the aniline benzene ring. The two aromatic rings are tilted relative to each other by 68.9 (1)°. N-H⋯O hydrogen bonds connect the mol-ecules into centrosymmetric dimers.
متن کاملN-(2,6-Dichlorophenyl)benzenesulfonamide
In the title compound, C(12)H(9)Cl(2)NO(2)S, the mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of 82.5 (2)°. The benzene rings are tilted relative to each other by 43.5 (1)°. The crystal structure features chains linked by N-H⋯O hydrogen bonds.
متن کامل2,4-Dichloro-N-(2,3-dichlorophenyl)benzenesulfonamide
In the title compound, C(12)H(7)Cl(4)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to the S=O bonds. Further, the N-H bond in the C-SO(2)-NH-C segment is syn with respect to the ortho-Cl atoms in the aniline and sulfonyl benzene rings. The C-SO(2)-NH-C torsion angle is -51.98 (18)°. The sulfonyl and aniline benzene rings are tilted by 67.7 (1)° rela...
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